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Non-Equilibrium Applications of Statistical Thermodynamics
  • Level Expert
  • Duration 8 hours
  • Course by University of Colorado Boulder
  • Offered by

About

Course 5 of Statistical Thermodynamics explores three different applications of non-equilibrium statistical thermodynamics. The first is the transport behavior of ideal gases, with some discussion of transport in dense gases and liquids. It starts with simple estimates of the transport properties of an ideas gas. It then introduces the Boltzmann Equation and describes the Chapman-Enskog solution of that equation in order to obtain the transport properties. It closes with a discussion of practical sources of transport properties. Spectroscopic methods have become increasingly common as a way of determining the thermodynamic state of a system. Here we present the underlying concepts of the subject and explores how spectroscopy can be used to determine thermodynamic and flow properties. Chemical kinetics are important in a variety of fluid/thermal applications including combustion, air quality, fuel cells and material processing. Here we cover the basics of chemical kinetics, with a particular focus on combustion. It starts with some definitions, including reaction rate and reaction rate constant. It then explores methods for determining reaction rate constants. Next, systems of reactions, or reaction mechanisms, are explored, including the oxidation of hydrogen and hydrocarbon fuels. Finally, computational tools for carrying out kinetic calculations are explored.

Modules

Video 1: A Molecular Picture of Dynamic Behavior

    • 1 Videos
    • 1 Readings
    • 1 Assignment
Show info about module content

1 Assignment

  • Problem 12.1

1 Videos

  • A Molecular Picture of Dynamic Behavior

1 Readings

  • A Molecular Picture of Dynamic Behavior

Video 2: Simple Kinetic Theory of Dilute Gases

    • 1 Videos
    • 1 Readings
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1 Videos

  • Simple Kinetic Theory of Dilute Gases

1 Readings

  • Simple Kinetic Theory of Dilute Gases

Video 3: Transport Properties

    • 1 Videos
    • 1 Readings
    • 2 Discussion
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2 Discussions

  • Problem 12.2
  • Problem 12.3

1 Videos

  • Transport Properties

1 Readings

  • Transport Properties

Video 4: The Boltzmann Equation, the Chapman-Enskog Solutions and Sources of Properties

    • 1 Videos
    • 1 Readings
    • 1 Discussion
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1 Discussions

  • Problem 12.4

1 Videos

  • The Boltzmann Equation and the Chapman- Enskog Solutions

1 Readings

  • The Boltzmann Equation and the Chapman-Enskog Solutions

Video 1: Spectroscopy

    • 1 Videos
    • 1 Readings
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1 Videos

  • Spectroscopy

1 Readings

  • Spectroscopy

Video 2: Atomic and Molecular Transitions

    • 1 Videos
    • 1 Readings
    • 1 Assignment
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1 Assignment

  • Problem 13.1

1 Videos

  • Atomic and Molecular Transitions

1 Readings

  • Atomic and Molecular Transitions

Video 3: The Radiative Transfer Equation and Absorption/Emission Spectroscopy

    • 1 Videos
    • 1 Readings
    • 1 Discussion
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1 Discussions

  • Problem 13.2

1 Videos

  • The Radiative Transfer Equation and Absorption and Emission Spectroscopy

1 Readings

  • The Radiative Transfer Equation and Absorption and Emission Spectroscopy

Video 4: Laser Induced Fluorescence Spectroscopy

    • 1 Videos
    • 1 Readings
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1 Videos

  • Laser Induced Fluorescence Spectroscopy

1 Readings

  • Laser Induced Fluorescence Spectroscopy

Video 5: Rayleigh Scattering

    • 1 Videos
    • 1 Readings
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1 Videos

  • Rayleigh Scattering

1 Readings

  • Rayleigh Scattering

Video 6: Raman Scattering

    • 1 Videos
    • 1 Readings
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1 Videos

  • Raman Scattering

1 Readings

  • Raman Scattering

Video 1: Chemical Reactions, Rates and the Reaction Rate Constant

    • 1 Videos
    • 1 Readings
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1 Videos

  • Chemical Reactions, Rates and the Reaction Rate Constant

1 Readings

  • Chemical Reactions, Rates and the Reaction Rate Constant

Video 2: Simple Reaction Rate Constant Theory

    • 1 Videos
    • 1 Readings
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1 Videos

  • Simple Reaction Rate Constant Theory

1 Readings

  • Simple Reaction Rate Constant Theory

Video 3: Reacting Systems: Chain Reactions

    • 1 Videos
    • 1 Readings
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1 Videos

  • Reacting Systems: Chain Reactions

1 Readings

  • Reacting Systems: Chain Reactions

Video 4: Unimolecular Reactions

    • 1 Videos
    • 1 Readings
    • 1 Assignment
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1 Assignment

  • Problem 14.1

1 Videos

  • Unimolecular Reactions

1 Readings

  • Unimolecular Reactions

Video 5: Hydrogen and Hydrocarbon Oxidation

    • 1 Videos
    • 1 Readings
    • 1 Assignment
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1 Assignment

  • Problem 14.2

1 Videos

  • Hydrogen and Hydrocarbon Oxidation

1 Readings

  • Hydrogen and Hydrocarbon Oxidation

Video 6: Numerical Methods for Chemical Kinetics

    • 1 Videos
    • 1 Readings
    • 1 Discussion
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1 Discussions

  • Problem 14.3

1 Videos

  • Numerical Methods for Chemical Kinetics

1 Readings

  • Numerical Methods for Chemical Kinetics

Auto Summary

Embark on an advanced journey into the realm of Statistical Thermodynamics with the course "Non-Equilibrium Applications of Statistical Thermodynamics." This specialized program is tailored for those in Science & Engineering, offering in-depth exploration into three pivotal areas of non-equilibrium statistical thermodynamics. Guided by expert insights from Coursera, this expert-level course delves into the transport behavior of ideal and dense gases, introducing the Boltzmann Equation and the Chapman-Enskog solution. Participants will gain practical knowledge about spectroscopic methods for determining thermodynamic states and flow properties. Additionally, the course covers chemical kinetics with a focus on combustion, exploring reaction rates, mechanisms, and computational tools for kinetic calculations. Spanning 480 minutes of comprehensive content, this course promises to equip learners with the expertise needed for advanced applications in fluid and thermal sciences. Subscription options are available with the Starter plan, making it accessible for dedicated learners keen on mastering these complex concepts. Ideal for those poised to deepen their understanding and application of statistical thermodynamics in various scientific and engineering contexts.

John W. Daily
Instructor

John W. Daily